Graphene-like quaternary compound SiBCN: a new wide direct band gap semiconductor predicted by a first-principles study

Due to the lack of two-dimensional silicon-based semiconductors and the fact that most of the components and devices are generated on single-crystal silicon or silicon-based substrates in modern industry, designing two-dimensional silicon-based semiconductors is highly desired. With the combination of a swarm structure search method and density functional theory in this work, a quaternary compound SiBCN with graphene-like structure is found and displays a wide direct band gap as expected. The band gap is of ~2.63 eV which is just between ~2.20 and ~3.39 eV of the highlighted semiconductors SiC and GaN. Notably, the further calculation reveals that SiBCN possesses high carrier mobility with ~5.14x10^3 and ~13.07x10^3 cm^2V^-1s^-1 for electron and hole, respectively. Furthermore, the ab initio molecular dynamics simulations also show that the graphene-like structure of SiBCN can be well kept even at an extremely high temperature of 2000 K. The present work tells that designing ulticomponent silicides may be a practicable way to search for new silicon-based low-dimensional semiconductors which can match well with the previous Si-based substrates

Substrate-induced half-metallic property in epitaxial silicene

For most practical applications in electronic devices, two-dimensional materials should be transferred onto semiconducting or insulating substrates, since they are usually generated on metallic substrates. However, the transfer often leads to wrinkles, damages, contaminations and so on which would destroy the intrinsic properties of samples. Thus, generating two-dimensional materials directly on nonmetallic substrates has been a desirable goal for a long time. Here, via a swarm structure search method and density functional theory, we employed an insulating N-terminated cubic boron nitride(111) surface as a substrate for the generation of silicene. The result shows that the silicene behaves as a ferromagnetic half-metal because of the strong interaction between silicon and surface nitrogen atoms. The magnetic moments are mainly located on surface nitrogen sites without bonding silicon atoms and the value is about 0.12 uB. In spin-up channel, it behaves as a direct band gap semiconductor with a gap of around 1.35 eV, while it exhibits metallic characteristic in spin-down channel, and the half-metallic band gap is about 0.11 eV. Besides, both the magnetic and electronic properties are not sensitive to the external compressive strain. This work maybe open a way for the utility of silicene in spintronic field

Numerical modeling of complex hydraulic fracture development in unconventional reservoirs

textSuccessful creations of multiple hydraulic fractures in horizontal wells are critical for economic development of unconventional reservoirs. The recent advances in diagnostic techniques suggest that multi-fracturing stimulation in unconventional reservoirs has often caused complex fracture geometry. The most important factors that might be responsible for the fracture complexity are fracture interaction and the intersection of the hydraulic and natural fracture. The complexity of fracture geometry results in significant uncertainty in fracturing treatment designs and production optimization. Modeling complex fracture propagation can provide a vital link between fracture geometry and stimulation treatments and play a significant role in economically developing unconventional reservoirs. In this research, a novel fracture propagation model was developed to simulate complex hydraulic fracture propagation in unconventional reservoirs. The model coupled rock deformation with fluid flow in the fractures and the horizontal wellbore. A Simplified Three Dimensional Displacement Discontinuity Method (S3D DDM) was proposed to describe rock deformation, calculating fracture opening and shearing as well as fracture interaction. This simplified 3D method is much more accurate than faster pseudo-3D methods for describing multiple fracture propagation but requires significantly less computational effort than fully three-dimensional methods. The mechanical interaction can enhance opening or induce closing of certain crack elements or non-planar propagation. Fluid flow in the fracture and the associated pressure drop were based on the lubrication theory. Fluid flow in the horizontal wellbore was treated as an electrical circuit network to compute the partition of flow rate between multiple fractures and maintain pressure compatibility between the horizontal wellbore and multiple fractures. Iteratively and fully coupled procedures were employed to couple rock deformation and fluid flow by the Newton-Raphson method and the Picard iteration method. The numerical model was applied to understand physical mechanisms of complex fracture geometry and offer insights for operators to design fracturing treatments and optimize the production. Modeling results suggested that non-planar fracture geometry could be generated by an initial fracture with an angle deviating from the direction of the maximum horizontal stress, or by multiple fracture propagation in closed spacing. Stress shadow effects are induced by opening fractures and affect multiple fracture propagation. For closely spaced multiple fractures growing simultaneously, width of the interior fractures are usually significantly restricted, and length of the exterior fractures are much longer than that of the interior fractures. The exterior fractures receive most of fluid and dominate propagation, resulting in immature development of the interior fractures. Natural fractures could further complicate fracture geometry. When a hydraulic fracture encounters a natural fracture and propagates along the pre-existing path of the natural fracture, fracture width on the natural fracture segment will be restricted and injection pressure will increase, as a result of stress shadow effects from hydraulic fracture segments and additional closing stresses from in-situ stress field. When multiple fractures propagate in naturally fracture reservoirs, complex fracture networks could be induced, which are affected by perforation cluster spacing, differential stress and natural fracture patterns. Combination of our numerical model and diagnostic methods (e.g. Microseismicity, DTS and DAS) is an effective approach to accurately characterize the complex fracture geometry. Furthermore, the physics-based complex fracture geometry provided by our model can be imported into reservoir simulation models for production analysis.Petroleum and Geosystems Engineerin

The Ideological Explorations of Chinese Communist Party and Chinese Kuomintang on Peacefully and Democratically Founding a New China

During the old Political Consultative Conference, Chinese Communist Party (CCP) and Chinese Kuomintang (KMT) both raised the idea of peacefully and democratically founding a new China, that is, under the condition of peace, to draw up the draft constitution, determine the principle of universal suffrage, hold a national people’s conference, and eventually establish a democratic constitutional coalition government; however, on the specific procedures, the two parties had quite different founding ideologies. The old Political Consultative Conference is a judgment to the political wisdom of both sides. Therefore, the CCP delegation has conducted a fierce political contest with the KMT delegation in the outline of peacefully founding the country, government organization plan, National Conference plan, Draft Constitution and other founding ideological aspects, made the Political Consultative Conference enact the agreement in favor of the people, which brought about a profound impact to China’s politics in the future

Attitudinal Shifts between The Newcomer and its English Translations: A Quantitative Exploration with Contextualization

Drawing on the framework of Appraisal Theory and inferential statistics, the present study examines possible attitudinal shifts between The Newcomer --- an influential Chinese short story of the communist theme and its two English translations. Such shifts are quantitatively explored in terms of the categories, block densities and prosodies of attitudinal units, revealing some typological and pragmatical features of the attitudes under translation. It is found that such attitudinal shifts may stem from certain contextual factors (e.g. linguistic distance, cultural diversity, ideological gap) that prompt the translators to adjust their translating strategies for attitudinal adaptions. Meanwhile, the effects of these attitudinal shifts upon different target readers are varied

Numerical modeling of complex hydraulic fracture development in unconventional reservoirs

textSuccessful creations of multiple hydraulic fractures in horizontal wells are critical for economic development of unconventional reservoirs. The recent advances in diagnostic techniques suggest that multi-fracturing stimulation in unconventional reservoirs has often caused complex fracture geometry. The most important factors that might be responsible for the fracture complexity are fracture interaction and the intersection of the hydraulic and natural fracture. The complexity of fracture geometry results in significant uncertainty in fracturing treatment designs and production optimization. Modeling complex fracture propagation can provide a vital link between fracture geometry and stimulation treatments and play a significant role in economically developing unconventional reservoirs. In this research, a novel fracture propagation model was developed to simulate complex hydraulic fracture propagation in unconventional reservoirs. The model coupled rock deformation with fluid flow in the fractures and the horizontal wellbore. A Simplified Three Dimensional Displacement Discontinuity Method (S3D DDM) was proposed to describe rock deformation, calculating fracture opening and shearing as well as fracture interaction. This simplified 3D method is much more accurate than faster pseudo-3D methods for describing multiple fracture propagation but requires significantly less computational effort than fully three-dimensional methods. The mechanical interaction can enhance opening or induce closing of certain crack elements or non-planar propagation. Fluid flow in the fracture and the associated pressure drop were based on the lubrication theory. Fluid flow in the horizontal wellbore was treated as an electrical circuit network to compute the partition of flow rate between multiple fractures and maintain pressure compatibility between the horizontal wellbore and multiple fractures. Iteratively and fully coupled procedures were employed to couple rock deformation and fluid flow by the Newton-Raphson method and the Picard iteration method. The numerical model was applied to understand physical mechanisms of complex fracture geometry and offer insights for operators to design fracturing treatments and optimize the production. Modeling results suggested that non-planar fracture geometry could be generated by an initial fracture with an angle deviating from the direction of the maximum horizontal stress, or by multiple fracture propagation in closed spacing. Stress shadow effects are induced by opening fractures and affect multiple fracture propagation. For closely spaced multiple fractures growing simultaneously, width of the interior fractures are usually significantly restricted, and length of the exterior fractures are much longer than that of the interior fractures. The exterior fractures receive most of fluid and dominate propagation, resulting in immature development of the interior fractures. Natural fractures could further complicate fracture geometry. When a hydraulic fracture encounters a natural fracture and propagates along the pre-existing path of the natural fracture, fracture width on the natural fracture segment will be restricted and injection pressure will increase, as a result of stress shadow effects from hydraulic fracture segments and additional closing stresses from in-situ stress field. When multiple fractures propagate in naturally fracture reservoirs, complex fracture networks could be induced, which are affected by perforation cluster spacing, differential stress and natural fracture patterns. Combination of our numerical model and diagnostic methods (e.g. Microseismicity, DTS and DAS) is an effective approach to accurately characterize the complex fracture geometry. Furthermore, the physics-based complex fracture geometry provided by our model can be imported into reservoir simulation models for production analysis.Petroleum and Geosystems Engineerin

Computing matrix inversion with optical networks

With this paper we bring about a discussion on the computing potential of complex optical networks and provide experimental demonstration that an optical fiber network can be used as an analog processor to calculate matrix inversion. A 3x3 matrix is inverted as a proof-of-concept demonstration using a fiber network containing three nodes and operating at telecomm wavelength. For an NxN matrix, the overall solving time (including setting time of the matrix elements and calculation time of inversion) scales as O(N^2), whereas matrix inversion by most advanced computer algorithms requires ~O(N^2.37) computational time. For well-conditioned matrices, the error of the inversion performed optically is found to be less than 3%, limited by the accuracy of measurement equipment.Comment: 5 page